Export

Link to this page

Please use this URL for citations.

Search Other Services

Statistics

  • Access to this page：3,015 times

＜departmental bulletin paper＞
Synthesis and Stereochemical Behavior of Ketoester Derivatives having trans -Cyclononene Skeleton

Creator
Author PID
L002986
Creator Name
井上, 寛子
Inoue, Hiroko
イノウエ, ヒロコ
Affiliation
Affiliation Name
九州大学大学院総合理工学府物質理工学専攻博士課程
Department of Molecular and Material Sciences, Interdisciplinary Graduate School of Engineering Sciences, Kyushu University
Author PID
K003109
Creator Name
井川, 和宣
Igawa, Kazunobu
イノカワ, カズノブ
Affiliation
Affiliation Name
九州大学大学院総合理工学府物質理工学専攻博士課程
Department of Molecular and Material Sciences, Interdisciplinary Graduate School of Engineering Sciences, Kyushu University
Author PID
K003087
Creator Name
友岡, 克彦
Tomooka, Katsuhiko
トモオカ, カツヒコ
Affiliation
Affiliation Name
九州大学先導物質化学研究所分子集積化学部門
Institute for Materials Chemistry and Engineering, Kyushu University
Language
Japanese
Publisher
九州大学大学院総合理工学府
Interdisciplinary Graduate School of Engineering Sciences, Kyushu University
Date
2010-11
Source Title
Engineering sciences reports, Kyushu University
Vol
32
Issue
3
First Page
19
Last Page
22
Publication Type
Version of Record
Access Rights
open access
JaLC DOI
https://doi.org/10.15017/18543
Related DOI
九州大学大学院総合理工学報告 || 32(3) || p19-22
Engineering sciences reports, Kyushu University || 32(3) || p19-22
http://www.tj.kyushu-u.ac.jp/
http://www.tj.kyushu-u.ac.jp/info/online/
Related URI
九州大学大学院総合理工学報告 || 32(3) || p19-22
Engineering sciences reports, Kyushu University || 32(3) || p19-22
http://www.tj.kyushu-u.ac.jp/
http://www.tj.kyushu-u.ac.jp/info/online/
Relation
九州大学大学院総合理工学報告 || 32(3) || p19-22
Engineering sciences reports, Kyushu University || 32(3) || p19-22
http://www.tj.kyushu-u.ac.jp/
http://www.tj.kyushu-u.ac.jp/info/online/
Abstract It has been found that the enolate formation followed by the alkylation of cyclic ketoester 2 provides (pR*, S*)-1 predominantly as a kinetic product. Planar chirality of 1 is labile at ambient temper...ature, hence (pR*, S*)-1 easily isomerizes to thermodynamically more favorable (pS*, S*)-1.show more

Hide fulltext details.

pdf full-32-3-4 pdf 1.84 MB 341  

Details

Record ID
18543
Peer-Reviewed
Refereed
Subject Terms
Ketoester, Alkylation
Dynamic Chirality
Planar Chirality
ISSN
1346-7883
NCID
AA1147319X
Created Date 2010.11.16
Modified Date 2020.11.27

People who viewed this item also viewed