Mendeley出力
＜紀要論文＞
Practical Procedures for Hydrosilylation of Ketones and Silane-induced Ring-opening Polymerization of Cyclic Ethers by Prior Activation of the Cluster Catalyst by Hydrosilanes : Improved Synthetic Procedures and Mechanistic Implication on the Catalytically Active Species
| 作成者 | |
|---|---|
| 本文言語 | |
| 出版者 | |
| 発行日 | |
| 収録物名 | |
| 巻 | |
| 号 | |
| 開始ページ | |
| 終了ページ | |
| 出版タイプ | |
| アクセス権 | |
| JaLC DOI | |
| 関連DOI | |
| 関連URI | |
| 関連情報 | |
| 概要 | Pre-activation of (μ_2,η^2:η^3:η^5-acenaphthylene)Ru_3(CO)_7 (1) by hydrosilanes in a small amount of dioxane provides novel convenient and useful procedures for hydrosilylation of carbonyl compounds ...and silane-induced ring-opening polymerization of cyclic ethers and a cyclic siloxane. The initial step of the catalytic cycle was investigated by NMR detection of products formed by the oxidative addition ofhydrosilanes to 1. A possibility for the involvement of cluster species in the catalytic cycle is discussed.続きを見る |
本文ファイル
| ファイル | ファイルタイプ | サイズ | 閲覧回数 | 説明 |
|---|---|---|---|---|
KJ00004507972
|
724 KB | 298 |
詳細
| レコードID | |
|---|---|
| 査読有無 | |
| ISSN | |
| NCID | |
| タイプ | |
| 登録日 | 2009.04.22 |
| 更新日 | 2020.12.09 |