| 作成者 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
| 本文言語 |
|
| 出版者 |
|
| 発行日 |
|
| 収録物名 |
|
| 巻 |
|
| 号 |
|
| 開始ページ |
|
| 終了ページ |
|
| 出版タイプ |
|
| アクセス権 |
|
| 権利関係 |
|
| 権利関係 |
|
| 関連DOI |
|
| 関連URI |
|
| 関連HDL |
|
| 概要 |
This study focused on evaluating the catalytic properties for the reverse water gas shift reaction (RWGS: CO_2 + H_2 → CO + H_2O ΔH^0 = 42.1 kJ mol^<−1>) in the presence of hydrogen sulfide (H_2S) ove...r a Fe/CeO_2 catalyst, commercial Cu–Zn catalyst for the WGS reaction (MDC-7), and Co–Mo catalyst for hydrocarbon desulfurization. The Fe/CeO_2 catalyst exhibited a relatively high catalytic activity to RWGS, compared to the commercial MDC-7 and Co–Mo catalysts. In addition, the Fe/CeO_2 catalyst showed stable performance in the RWGS environment that contained high concentrations of H_2S. The role of co-feeding H_2S was investigated over the Fe/CeO_2 catalyst by the temperature programmed reaction (TPR) of CO_2 and H_2 in the presence of H_2S. The result of TPR indicated that the co-feeding H_2S might enhance RWGS performance due to H_2S acting as the hydrogen source to reduce CO_2.続きを見る
|
Mendeley出力
