| 作成者 |
|
|
|
|
|
| 本文言語 |
|
| 出版者 |
|
|
|
| 発行日 |
|
| 収録物名 |
|
| 巻 |
|
| 号 |
|
| 開始ページ |
|
| 終了ページ |
|
| 出版タイプ |
|
| アクセス権 |
|
| JaLC DOI |
|
| 関連DOI |
|
|
|
|
|
| 関連URI |
|
|
|
|
|
| 関連情報 |
|
|
|
|
|
| 概要 |
A new synthetic method consisting of a hydroboration/imine reduction sequence is described. Hydroboration of 3-[(1-phenylethylidene) amino]-propene with optically pure isopinocanpheylborane is followe...d by the reaction with diethylzinc and then the oxidation with hydrogen peroxide to produce 3-(1-phenylethylamino)-1-propanol with a moderate enantioselectivity. The alkylborane produced in the hydroboration step forms a chiral five-membered complex structure which induces the new chirality in the imine reduction step.続きを見る
|
Mendeley出力
KJ00004507701