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Medium-sized (E)-alkenes have aroused interest in structural organic chemistry and synthetic organic chemistry because of their unique stereochemical properties and reactivity. However efficient synth...etic methods to approach medium-sized (E)-alkenes have been quite limited owing to their high strain. To this end, we have developed E-selective photochemical isomerization using selective adsorption property of AgNO_3-impregnated silica-gel toward strained (E)-alkene, which allows efficient synthesis of medium-sized (E)-alkenes from more accessible Z isomers.続きを見る
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