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As a part of our research on chemistry of planar chiral medium-sized heterocyclic molecules, C3-methyl substituted nine-membered diallylic amide 1ab and C4-methyl substituted congener 1ac have been sy...nthesized and their stereochemical behavior were evaluated and compared with non-substituted congener 1aa. The degree and order of stereochemical stability shows the significant substituent effect; substituent on C3 position increases the stereochemical stability of 1aa in sharp contrast to the that of on C4 position decreases it.続きを見る
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