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Computer simulation has been carried out to study conformation of poly (macromonomer), a comb polymer with a long branch in every monomeric unit. Effects of the main backbone chain length as well as t...he side chain length on the shape of poly (macromonomer) are examined using the bond fluctuation model in the simulation. We find that the shape of the main chain varies from a coil form to an extended form as the side chain length increases. The main chain axis has same direction as the main axis of poly (macromonomer) in the extended state. The side chain keeps a coil form irrespective of conformation of the main chain.続きを見る
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