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Structure and Dynamics of Weakly Bound Molecular Complexes

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概要 The study of weakly bound molecular complexes has in recent years brought this field of investigation to the forefront of physical and chemical research. The scope of the subject is wide and different... terminology and nomenclature is current among the various subspecialties. Thus, the term "metal cluster" often connotes to the organic chemist a metal-organic compound, while the physicist will more likely think of groups of metal atoms held together by weak interatomic forces. Aggregates, clusters, complexes, van der Waals molecules, hydrogen-bonded molecules, etc. are terms currently in use, sometimes interchangeably while other times with well defined and mutually exclusive meanings. The subjects of this volume are the free, isolated vim der Waals and hydrogen-bonded molecules. Owing to the present state of experimental knowledge these are mostly dimers, i. e. , entities formed by two strongly bound molecules, an atom and a molecule, or two atoms held together by the weak hydrogen-bonding, or the still weaker van der Waals forces. Weakly bound complexes formed of more than two strongly bound sub-units, i. e. , trimers, tetramers, etc. , are now coming within reachof experimental observation and several papers in this book deal with them. The study of van der Waals and hydrogen-bonded interactions has been pursued for several decades. Most of these ,investigations have, however, dealt with systems in the condensed phase in which bulk effects are commingled with and therefore mask the weak binary interactions.続きを見る
目次 I. Spectroscopy, Structure, Potentials
A. Rotational Spectra
Rotational Spectroscopy of Weakly Bound Complexes: Capabilities and Limitations
Pulsed-Nozzle, Fourier-Transform Microwave Spectroscopy of Hydrogen-Bonded Dimers
Structure Determination of Weakly Bound Complexes
Microwave Spectra and Weak Intramolecular Hydrogen Bonding in 3-Butene-1-Thiol and N-Methylallylamine
B. Rotation-Vibrational Spectra
High Resolution Infrared Spectroscopy of van der Waals Molecules
Vibration-Rotation Spectroscopy of ArHCl by Far-Infrared Laser and Microwave/Far-Infrared Laser Double Resonance Spectroscopy
Vibrational Anomalies and Dynamic Coupling in Hydrogen-Bonded van der Waals Molecules
Slit Jet IR Absorption Spectroscopy of Molecular Complexes
Sub-Doppler Resolution Infrared Spectroscopy of Binary Molecular Complexes
The Infrared Spectrum of H2-Ar: New Observations in the v=l-0 and 2-0 Bands of H2
Dynamical Properties of Simple Hydrogen-Bonded Clusters
Infrared Spectroscopy of Hydrogen-Bonded and van der Waals Complexes
Ab Initio Calculations of Vibrational Frequencies and Infrared Intensities for the Hydrogen- Bonded Complex HCN-HF
The Role of Tunneling Models in Analyzing High- Resolution Spectra of Weakly Bound Molecular Complexes
Bibliography of Rotational Spectra of Weakly Bound Complexes
C. Electronic Spectra
Structure and Dynamics of Mercury van der Waals Complexes
The Structure of van der Waals Molecules of s-Tetrazine
Spectra of Mixed Dimers
Solvent Shifts, Spectroscopy and Structure in van der Waals Complexes of Perylene
Spectroscopy in the Visible and Near Ultraviolet Region of Some Organic Molecules and their van der Waals Complexes
Supersonic Jet Spectroscopy of Complexes of Carbazole and N-Ethyl Carbazole with Alkyl Cyanides
Photoionization of Hydrogen-Bonded Molecular Aggregates
D. Potential Functions
The Unavoidable Importance of Electrostatic Effects in the Structures of Weakly Bonded Complexes
Intermolecular Potentials, Internal Motions and the Spectra of van der Waals Molecules
Non-Bonding Atom-Diatom Potentials via a Double Many-Body Expansion Method
The Determination of Intermolecular Forces by Data Inversion Methods
Transport Properties of van der Waals Molecules Computed from Accurate Interactions
Determination of Anisotropic Interaction Potentials from Rotational State Resolved Scattering Data
van der Waals Interactions from Glory and Diffraction Scattering
High Resolution Crossed Molecular Beam Studies of van der Waals Forces
E. Summary: Part
Where Are We in Weak Intermolecular Interactions?
II. Dynamics
Interpretation of Linewidths in the Infrared Photodissociation Spectra of van der Waals Molecules
Infrared Photodissociation of van der Waals Complexes Selectively Prepared by Molecular Beam Scattering
IR Dissociation of Weakly Bound van der Waals Complexes: (SF6)n, (SiF4)n, (SiH4)n, (C2H4)n,(n=2,3) in the 9-11 in ?m Range
Infrared (9-11?m) Dissociation of the Hydrogen Bonded Clusters (NH3)n (n?2)Detected by Bolometric Technique
Highly Excited Systems
Vibrational Predissociation Dynamics of the Nitric Oxide Dimer
Complex Forming Reactions in Noble Gas Clusters
Structure and Dynamics of the Rare Gas-Halogen van der Waals Molecules: Product State Distributions for Vibrational Predissociation of NeBr2
Dynamics of Energy Transfer in van der Waals Molecules of s-Tetrazine and Argon
Theory of van der Waals Photofragmentation Dynamics
Dissociation Dynamics of the He-I2-Ne van der Waals Complex
Dynamics of the Ar
-H2 van der Waals Complex: A Diabatic Distorted Wave Approach Including Discrete-Discrete Couplings
Vibrational Predissociation Dynamics of Weakly Bonded Dimers: A Summary
List of Participants
List of Contributors
List of Poster Papers
List of Names.
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登録日 2020.06.27
更新日 2020.06.28