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Mixed-Valence Compounds : Theory and Applications in Chemistry, Physics, Geology, and Biology

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概要 It has been a decade since two seminal reviews demonstrated that mixed-valence compounds share many unique and fascinating features. The insight pro vided by those early works has promoted a great dea...l of both experimental and theoretical study. As a result of extensive efforts, our understanding of the bonding and properties of mixed-valence compounds has advanced substantially. There has been no compre hensive treatment of mixed-valence compounds since 1967, and the meeting convened at Oxford in September, 1979, provided a unique opportunity to examine the subject and its many ramifications. Mixed-valence compounds play an important role in many fields. Although the major impact of the subject has been in chemistry, its importance has become increasingly clear in solid state physics, geology, and biology. Extensive interest and effort in the field of molecular metals has demonstrated that mixed-valency is a prerequisite for high elec trical conductivity. The intense colors of many minerals have been shown to be due to mixed-valency, and the electron-transfer properties of certain mixed-valence metalloproteins are important in biological processes. Experts from all of these areas participated in this meeting, and the truly interdisciplinary nature of the subject made it a unique learning experience for all in attendance.続きを見る
目次 I. An Overview of Mixed-Valency
to Mixed-Valence Chemistry
Descriptive Chemistry of Mixed-Valence Compounds
Synthetic Approaches to Mixed-Valence Chemistry
II. Models for the Mixed-Valence State
Electron Transfer in Mixed-Valence Compounds
A Vibronic Coupling Model for Mixed-Valence Compounds and its Application to Real Systems
Electron Delocalization, Structure and Dynamics in Mixed-Valence Systems
III. Experimental Probes to Mixed-Valence Compounds
Magnetism of Mixed-Valence Compounds
Applications of the Mössbauer Effect to the Study of Mixed-Valence Compounds
Electronic, Raman, and Resonance-Raman Spectroscopic Studies of Mixed-Valence Complexes
IV. Classes of Mixed-Valence Materials
Mixed-Valence Minerals of Iron and Titanium: Correlations of Structural, Mössbauer and Electronic Spectral Data
Mixed-Valency in Discrete and Condensed Transition Metal Cluster Species With Classical Ligands
Heteropoly Blues
Linear Chain Mixed-Valence Systems with Direct Metal-Metal Interactions
The Verwey Transition Revisited
Polymetallic Centers in Biology
Mixed-Valence in the Organic Solid State
Photoelectron Spectroscopy of Mixed-Valence Compounds
List of Contribution to the Discussion Sessions.
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登録日 2020.06.27
更新日 2020.06.28