<紀要論文>
Complexation and Fluorescence Behavior of Tris[(1-naphthoyloxy)ethyl]amine

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概要 Tris[(1-naphthoyloxy)ethyl]amine (1) was found to display unique photophysical properties in the presence of the guest cations. The amine (1) revealed a broad emission band around 440nm that is typica...l of a structureless emission of a naphthoyl excimer and a naphthalene-amine exciplex. From the result of X-ray analysis, the amine (1) adopt a tripod conformation with crystallographic C_3 symmetry. Complexation of 1 with Al^<3+> increased the emission intensity of a factor by 5.3 in H_2O-CH_3OH (1:1 v/v).続きを見る

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登録日 2009.04.22
更新日 2017.06.07