| 作成者 |
|
|
|
| 本文言語 |
|
| 出版者 |
|
|
|
| 発行日 |
|
| 収録物名 |
|
| 巻 |
|
| 号 |
|
| 開始ページ |
|
| 終了ページ |
|
| 出版タイプ |
|
| アクセス権 |
|
| JaLC DOI |
|
| 関連DOI |
|
|
|
|
|
| 関連URI |
|
|
|
|
|
| 関連情報 |
|
|
|
|
|
| 概要 |
[2.n]Metacyclophanes of which various kinds of functional groups were introduced into the aromatic rings have been synthesized in order to evaluate the specific through-space interaction in cyclophane... systems. The cationic character in the metacyclophanediazonium salts was found to be strongly affected by the electronic effect of the substituent on the opposite aromatic ring via the through-space interaction between two aromatic rings. Spectral properties of disubstituted metacyclophanes and stilbenophanes showed that a [2.n]metacyclophane can be regarded as a nonplanar molecule with one conjugated system due to a strong through-space interaction. Such an interaction of the [2.3]system has been proved to decreasein comparison with that of the [2.2]system.続きを見る
|
Mendeley出力
KJ00004507848