<紀要論文>
Synthesis, Structures and Inclusion Properties of [(Arenylaminocarbonyl) methoxy] hexahomotrioxacalix [3] arenes

作成者
本文言語
出版者
発行日
雑誌名
開始ページ
終了ページ
出版タイプ
アクセス権
JaLC DOI
概要 The lower rim functionalized homotrioxacalix[3]arene 4a and 4b were synthesized from triol 1 by a stepwise reaction. Extraction data for metal and ammonium picrates from water into dichloromethane are... discussed Due to the strong intramolecular hydrogen bonding between the neighboring NH and CO groups, their affinities as an ionophore to metal cations decreased cone-4a shows single selectivity to n-BuNH_3^+ while partial-cone-4a almost has no affinity to cations. cone-4b has high selectivity and affinity to Ag^+ cation. The complex mode of cone-4a with n-BuNH_3Cl wd cone-4b with Ag^+ was demonstrated by ^1H NMR titration in CDCl_3, respectively. A good Job plot proves 1:1 coordination of cone-4b with Ag^+ cation.続きを見る

本文情報を非表示

KJ00004507840 pdf 791 KB 96  

詳細

レコードID
査読有無
関連情報
ISSN
NCID
タイプ
登録日 2009.04.22
更新日 2017.06.07