<紀要論文>
Addition Reaction of 2-Pyrone-5-carboxylate with α-Terpinene. An Attempted Conversion of Monoterpene to Sesquiterpenoids

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概要 Methyl 2-pyrone-5-carboxylate reacted with α-terpinene site- and regio-selectively to give tricycle lactones at 110℃. At a higher temperature, decarboxylation and subsequent intramolecular cycloadditi...on took place to afford a triene and a tetracyclic ester. A triene diester and hydroxy diesters were synthesized from the lactones. Attempted conversion of them to eudesmanoids are described.続きを見る

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登録日 2009.04.22
更新日 2017.06.01