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Photo-induced proton transfer in tropolones has been undertaken to obtain information on the fundamentals and development of hydrogen-transfer laser and molecular memory. High resolution spectra in wh...ich rovibrational structure are resolved have been observed by using supersonic free-jet laser spectroscopy. The madnitude of tunneling splitting is discussed on the basis of vibrational-mode coupling to hydrogen-transfer coordinates and/or the symmetry of the doubleminimum potential of tropolones.続きを見る
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