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高次機能発現のための触媒設計 : ポリフルオロ置換ホウ素アート錯体の高脂溶性を利用する触媒効果

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概要 The article describes the molecular design of anionic phase transfer catalysts, which function as cationic-reagent carrier in hydrophobic organic media. Tetraphenyl-boron ate-complexes modified with p...olyfluorinated substituents could afford to provide highly lipophilic, chemically stable and bulky organic anions which satisfied requirements for the phase transfer catalysts. Cationic reagent, which is incorporated into hydrophobic organic media in the form of ion pair with the catalyst, can act as it is, or give rise to higher-order cationic reagents for subsequent novel reactions, some examples of which are exhibited.続きを見る

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登録日 2009.04.22
更新日 2017.03.28