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For syntheses of novel functional materials from non-benzenoid aromatic compounds particularly from troponoids, we have carried out studies on the lines of i) synthesis of dithiocrown ether derivative...s annexed to tropolone rings, which showed a selective mercury-capturing ability, ii) syntheses of liquid crystals whose outstanding properties were derived from the Woodward-Hoffmann rule-allowed [1,9] sigmatropic rearrangement of acyloxy groups, and iii) syntheses of J-aggregate dyes of polycondensed non-alternant aromatics, which constituted the first J-aggregating compounds in the polycondensed aromatic compounds.続きを見る
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