<紀要論文>
Metacyclophanes and Related Compounds. XXV. Generation of Bis (o-quinone methide) from [2.2] Metacyclophane Having Spiro Skeleton and Its Reactions with Alcohols, Acetic Acid, and Ethenes

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概要 Spiro compound 3 obtained in the oxidation of 8,16-dihydroxy[2.2]meta-cyclopnane 2 with Ag_2O, readily generated bis(o-quinone methide) 4 on mild heating, which was trapped with methanol, ethanol, ace...tic acid to give di-arylethane 5. [4+2]Cycloadduct 9 of 4 and ethene 8 was obtained when 3 was thermolyzed in the presence of 8 in refluxing benzene.続きを見る

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登録日 2009.04.22
更新日 2017.03.28