<紀要論文>
Fluorinated Tetraarylborates as Anionic Phase-transfer Catalysts : An Example of Molecular Design of Functional Fluoroaromatics

作成者
本文言語
出版者
発行日
雑誌名
開始ページ
終了ページ
出版タイプ
アクセス権
JaLC DOI
概要 Tetrakis [3,5-bis (trifluoromethyl) phenyl] borate (TFPB), a highly lipophilic fluoroaromatic borate ion which is remarkably stable under acid and oxidative conditions, was designed as an anionic phas...e-transfer catalyst, whose function is to transfer cationic species such as diazonium and oxonium ions in reactive form of ion pair from an aqueous (or solid) phase into a nonpolar organic phase and to promote catalytically the electrophilic reactions in two-phase systems. Some effective examples of anionic phase-transfer catalysis (PTC) with TFPB were demonstrated in the diazo coupling, the Friedel-Crafts alkylation, the nitrosation (in situ diazo coupling), the acid-mediated hydrolysis of esters, and the redox reactions with methylviologen in the liquid membrane system. Kinetic investigations of these PTC reactions clearly indicated that the enhanced reactivities of the cationic species and the specificities of the electrophilic reactions were due to the dehydration of such cationic species ion-paired with TFPB in nonpolar organic phase.続きを見る

本文情報を非表示

KJ00004507507 pdf 829 KB 243  

詳細

レコードID
査読有無
関連情報
ISSN
NCID
タイプ
登録日 2009.04.22
更新日 2017.03.22