Export Mendeley
＜departmental bulletin paper＞
Practical Procedures for Hydrosilylation of Ketones and Silane-induced Ring-opening Polymerization of Cyclic Ethers by Prior Activation of the Cluster Catalyst by Hydrosilanes : Improved Synthetic Procedures and Mechanistic Implication on the Catalytically Active Species
| Creator | |
|---|---|
| Language | |
| Publisher | |
| Date | |
| Source Title | |
| Vol | |
| Issue | |
| First Page | |
| Last Page | |
| Publication Type | |
| Access Rights | |
| JaLC DOI | |
| Related DOI | |
| Related URI | |
| Relation | |
| Abstract | Pre-activation of (μ_2,η^2:η^3:η^5-acenaphthylene)Ru_3(CO)_7 (1) by hydrosilanes in a small amount of dioxane provides novel convenient and useful procedures for hydrosilylation of carbonyl compounds ...and silane-induced ring-opening polymerization of cyclic ethers and a cyclic siloxane. The initial step of the catalytic cycle was investigated by NMR detection of products formed by the oxidative addition ofhydrosilanes to 1. A possibility for the involvement of cluster species in the catalytic cycle is discussed.show more |
Hide fulltext details.
| File | FileType | Size | Views | Description |
|---|---|---|---|---|
KJ00004507972
|
724 KB | 317 |
Details
| Record ID | |
|---|---|
| Peer-Reviewed | |
| ISSN | |
| NCID | |
| Type | |
| Created Date | 2009.04.22 |
| Modified Date | 2020.12.09 |