| Creator |
|
|
|
|
|
|
|
|
|
|
|
|
|
| Language |
|
| Publisher |
|
|
|
| Date |
|
| Source Title |
|
| Vol |
|
| Issue |
|
| First Page |
|
| Last Page |
|
| Publication Type |
|
| Access Rights |
|
| JaLC DOI |
|
| Related DOI |
|
|
|
|
|
|
|
|
|
|
|
|
|
| Related URI |
|
|
|
|
|
|
|
|
|
|
|
|
|
| Relation |
|
|
|
|
|
|
|
|
|
|
|
|
|
| Abstract |
Oxadiazolopyridine compounds have seen synthesized with the aim of preparing red fluorescent organic material for organic electrolum inescent devices. 10-Oxoindenooxadiazolopyridines, which were synth...esized from acetophenone derivatives in 4 steps, show red fluorescence in the solid state, albeit with a weak intensity. 10-Hydroxy derivatives emit fluorescence of yellow to orange color, however these compounds are instable in air. Oxadiazolopyridenes having thiophene and furan rings at the 4- and 7-positions, prepared from the corresponding heterocyclic methyl ketones, emit intense red fluorescence above 600nm in the solid state. Of special note is 4,7-di(5'-phenyl-2'-thienyl)oxadiazolopyridine which shows red fluorescence at 669nm. An EL device using 5'-phenyl-2'-thienyl derivative as a light-emitting materials was fabricated by Kyushu Matsushita corporation. This device emitted red EL at 680nm. In the cyclic voltammogram, oxadiazolopyridines show a reversible redox wave at -0.9～-1.17V. The oxadiazolopyridine ring having an electron-withdrawing substituent was reduced at low cathodic potential.show more
|
Export Mendeley
KJ00004507936