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The photoaddition reaction of methyl 2,4-dioxopentanoate with chloroprene gave two de Mayo type adducts, methyl 3-(1-chlorovinyl)-2, 6-dioxoheptanoate and methyl 3-chloro-2, 6-dioxo-3-vinyl-heptanoate.... No regio isomers, 4-substituted esters, were observed. The photoadducts were converted to cyclohexenones and the selectivity of photoaddition was discussed.show more
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