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| Abstract |
Diels-Alder adducts of C_<60> easily cycloreverted to the starting materials by heating. This property makes it difficult to determine the molecular weight of adducts by means of mass spectrometry. We... employed collision-activated dissociation spectra to characterize the Diels-Alder adducts of C_<60> with troponoids, cycloheptatriene, and 2-cycloalkenones and their acetals since the molecular peak of C_<60> as well as peaks derived from C_<60> were intense. This technique is useful for the determination of the molecular weight of thermally labile compounds.show more
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KJ00004507835