Creator |
|
|
|
|
|
|
Language |
|
Publisher |
|
Date |
|
Source Title |
|
Vol |
|
Issue |
|
First Page |
|
Last Page |
|
Publication Type |
|
Access Rights |
|
Rights |
|
Rights |
|
Related DOI |
|
Related URI |
|
Related HDL |
|
Abstract |
This paper reports the first example of a reductive C(sp^3)–C(sp^3) homo-coupling of benzyl/allyl halides in aqueous solution by using H_2 as an electron source {turnover numbers (TONs) = 0.5–2.3 for ...12 h}. This homo-coupling reaction, promoted by visible light, is catalysed by a water-soluble electron storage catalyst (ESC). The reaction mechanism, and four requirements to make it possible, are also described.show more
|