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This paper reports the first example of a reductive C(sp^3)–C(sp^3) homo-coupling of benzyl/allyl halides in aqueous solution by using H_2 as an electron source {turnover numbers (TONs) = 0.5–2.3 for ...12 h}. This homo-coupling reaction, promoted by visible light, is catalysed by a water-soluble electron storage catalyst (ESC). The reaction mechanism, and four requirements to make it possible, are also described.続きを見る
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