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The inorganic metal node and organic linker may be chemically transformed to optimize metal organic frameworks (MOFs) for various uses. The term zeolitic imidazolate framework (ZIF) refers to MOFs tha...t are topologically isomorphic with zeolites. These can be synthesized in several ways such as hydrothermal, sol gel, solvothermal etc. After the fabrication these can be modified with post synthetic modification (PSM) processes. The idea for PSM was developed in this century. PSM is a procedure that may be used to modify MOFs while still preserving the structural integrity of the framework. PSM makes it possible to functionalize both the metallic and organic components of MOFs. PSM acts as a technique for phase separation, increasing catalytic activity, increased surface area for surface reactions, and improvement of other properties. The purpose of this article is to give a mini overview of the various PSM approaches used for ZIF modification.続きを見る
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