Addition Reaction of 2-Pyrone-5-carboxylate with α-Terpinene. An Attempted Conversion of Monoterpene to Sesquiterpenoids - Collections

＜departmental bulletin paper＞
Addition Reaction of 2-Pyrone-5-carboxylate with α-Terpinene. An Attempted Conversion of Monoterpene to Sesquiterpenoids

Creator	Author PID K001850 Creator Name Hatsui, Toshihide 初井, 敏英ハツイ, トシヒデ Affiliation Affiliation Name Institute of Advanced Material Study Kyushu University 九州大学機能物質科学研究所
	Creator Name Hirata, Narukuni ヒラタ, ナルクニ Affiliation Affiliation Name Interdisciplinary Graduate School of Engineering Sciences, Kyushu University
	Author PID L000976 Creator Name Takeshita, Hitoshi 竹下, 齊タケシタ, ヒトシ Affiliation Affiliation Name Institute of Advanced Material Study Kyushu University 九州大学機能物質科学研究所
Language	English
Publisher	九州大学機能物質科学研究所
Publisher	Institute of Advanced Material Study Kyushu University
Date	1996-11-12
Source Title	The reports of Institute of Advanced Material Study Kyushu University
Vol	10
Issue	1
First Page	35
Last Page	39
Publication Type	Version of Record
Access Rights	open access
JaLC DOI	https://doi.org/10.15017/6690
Related DOI	九州大学機能物質科学研究所報告 \|\| 10(1) \|\| p35-39
	The reports of Institute of Advanced Material Study Kyushu University \|\| 10(1) \|\| p35-39
	http://www.cm.kyushu-u.ac.jp/
Related URI	九州大学機能物質科学研究所報告 \|\| 10(1) \|\| p35-39
	The reports of Institute of Advanced Material Study Kyushu University \|\| 10(1) \|\| p35-39
	http://www.cm.kyushu-u.ac.jp/
Relation	九州大学機能物質科学研究所報告 \|\| 10(1) \|\| p35-39
	The reports of Institute of Advanced Material Study Kyushu University \|\| 10(1) \|\| p35-39
	http://www.cm.kyushu-u.ac.jp/
Abstract	Methyl 2-pyrone-5-carboxylate reacted with α-terpinene site- and regio-selectively to give tricycle lactones at 110℃. At a higher temperature, decarboxylation and subsequent intramolecular cycloadditi...on took place to afford a triene and a tetracyclic ester. A triene diester and hydroxy diesters were synthesized from the lactones. Attempted conversion of them to eudesmanoids are described.show more

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Record ID	6690
Peer-Reviewed	Unrefereed
ISSN	0914-3793
NCID	AN10060378
Type	紀要論文
Type	一般論文
Created Date	2009.04.22
Modified Date	2020.11.02

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＜departmental bulletin paper＞ Addition Reaction of 2-Pyrone-5-carboxylate with α-Terpinene. An Attempted Conversion of Monoterpene to Sesquiterpenoids

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＜departmental bulletin paper＞
Addition Reaction of 2-Pyrone-5-carboxylate with α-Terpinene. An Attempted Conversion of Monoterpene to Sesquiterpenoids