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＜departmental bulletin paper＞
Synthetic Photochemistry. LXX. Efficient Formation of An Eudesmane Skeleton by the de Mayo Reaction between 1-Isopropyl-4-methylcyclohexa-1,3-diene and Methyl 2,4-Dioxopentanoate
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| Abstract | The de Mayo reaction of methyl 2,4-dioxopentanoate and 1-isopropyl-4-methylcyclohexa-1,3-diene afforded, together with an oxetane and a [4+2] adduct, a dihydropyran derivative, which gave an eudesmane... derivative by acid treatment. The dihydropyran and the [4+2] adduct were formed from the common intermediate.show more |
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| Created Date | 2009.04.22 |
| Modified Date | 2020.11.17 |