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＜departmental bulletin paper＞
Acid-Catalyzed Rearrangement of Tropone Endoperoxides. An 8,9-Dioxabicyclo [3.2.2] nona-3,6-diene Derivative to an 8-Oxabicyclo [3.2.1] octane Derivative
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| Abstract | Tropone endoperoxides rearranged to 8-oxabicyclo [3.2.1] octane derivatives by acid. In m-chloroperbenzoic acid-oxidation, an epoxy ring would assist the O-O bond cleavage to give a γ-hydroxyketone, w...hich cyclized to 8-oxabicyclo [3.2.1]octane derivatives.show more |
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| Created Date | 2009.04.22 |
| Modified Date | 2020.10.13 |