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Abstract |
8,9-ジヒドロホモバーレレノン誘導体はトランスアニュラーコンジュゲーションを示す興味ある双環状化合物である。その^<13>C NMRの化学シフトは構造解析に非常に有用な情報を与えた。本報告では関連化合物の構造解析に有効なそれら化学シフトに及ぼす置換基効果を整理して表示した。 The ^<13>C NMR chemical shifts of various dihydrohomobarreleno...nes, bicycle [3. 2. 2] hepta-3, 6-dien-2-ones, were compiled and compared each other. These conformationally rigid bicyclic compounds showed a good correlation on the substituent effects, which made the structure elucidations easy.show more
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