E-Selective Photochemical Isomerization of Medium-sized Alkene using Adsorption Property of AgNO_3-Impregnated Silica-Gel - Collections | Kyushu University Library

＜departmental bulletin paper＞
E-Selective Photochemical Isomerization of Medium-sized Alkene using Adsorption Property of AgNO_3-Impregnated Silica-Gel

Creator	Creator Name 吉田, 祐樹 YOSHIDA, Yuki ヨシダ, ユウキ Affiliation Affiliation Name 九州大学大学院総合理工学府物質理工学専攻 : 博士課程 Department of Mokecular and Material Sciences, Interdisciplinary Graduate School of Engineering, Kyushu University : Master's Program
	Creator Name 町田, 康平 MACHIDA, Kouhei マチダ, コウヘイ Affiliation Affiliation Name 九州大学大学院総合理工学府物質理工学専攻 : 博士課程 Department of Mokecular and Material Sciences, Interdisciplinary Graduate School of Engineering, Kyushu University : Master's Program
	Author PID K003109 Creator Name 井川, 和宣 IGAWA, Kazunobu イガワ, カズノブ Affiliation Affiliation Name 九州大学先導物質化学研究所分子集積化学部門 Department of Applied Molecular Chemistry, Institute for Materials Chemistry and Engineering, Kyushu University
	Author PID K003087 Creator Name 友岡, 克彦 TOMOOKA, Katsuhiko トモオカ, カツヒコ Affiliation Affiliation Name 九州大学先導物質化学研究所分子集積化学部門 Department of Applied Molecular Chemistry, Institute for Materials Chemistry and Engineering, Kyushu University
Language	Japanese
Publisher	Interdisciplinary Graduate School of Engineering Sciences, Kyushu University
Publisher	九州大学大学院総合理工学府
Date	2021-02
Source Title	Engineering sciences reports, Kyushu University
Vol	42
Issue	2
First Page	22
Last Page	26
Publication Type	Version of Record
Access Rights	open access
JaLC DOI	https://doi.org/10.15017/4479149
Abstract	Medium-sized (E)-alkenes have aroused interest in structural organic chemistry and synthetic organic chemistry because of their unique stereochemical properties and reactivity. However efficient synth...etic methods to approach medium-sized (E)-alkenes have been quite limited owing to their high strain. To this end, we have developed E-selective photochemical isomerization using selective adsorption property of AgNO_3-impregnated silica-gel toward strained (E)-alkene, which allows efficient synthesis of medium-sized (E)-alkenes from more accessible Z isomers.show more

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Record ID	4479149
Subject Terms	photochemical isomerization
	medium-sized alkene
	AgNO_3-impregnated silica-gel
ISSN	1346-7883
NCID	AA1147319X
Funding Information	Funder Name 日本学術振興会 Japan Society for the Promotion of Science Award Number 20H05677 Award Title キラル分子を光学活性体として得る革新的手法DYASINの開発 Development of DYASIN: Novel Approach to Enantioenriched Chiral Molecules
Funding Information	Funder Name 文部科学省先端研究基盤共用促進事業 Award Number JPMXS0422300120
Created Date	2021.06.15
Modified Date	2021.06.15