Stereodivergent Synthesis of Chiral Silacyclopentanes - Collections | Kyushu University Library

＜departmental bulletin paper＞
Stereodivergent Synthesis of Chiral Silacyclopentanes

Creator	Creator Name 黒尾, 明弘 KUROO, Akihiro クロオ, アキヒロ Affiliation Affiliation Name 九州大学大学院総合理工学府物質理工学専攻 : 博士課程 Department of Mokecular and Material Sciences, Interdisciplinary Graduate School of Engineering, Kyushu University : Master's Program
	Creator Name 吉廣, 大佑 YOSHIHIRO, Daisuke ヨシヒロ, ダイスケ Affiliation Affiliation Name 九州大学大学院総合理工学府物質理工学専攻 : 博士課程 Department of Mokecular and Material Sciences, Interdisciplinary Graduate School of Engineering, Kyushu University : Master's Program
	Author PID K003109 Creator Name 井川, 和宣 IGAWA, Kazunobu イガワ, カズノブ Affiliation Affiliation Name 九州大学先導物質化学研究所分子集積化学部門 Department of Applied Molecular Chemistry, Institute for Materials Chemistry and Engineering, Kyushu University
	Author PID K003087 Creator Name 友岡, 克彦 TOMOOKA, Katsuhiko トモオカ, カツヒコ Affiliation Affiliation Name 九州大学先導物質化学研究所分子集積化学部門 Department of Applied Molecular Chemistry, Institute for Materials Chemistry and Engineering, Kyushu University
Language	Japanese
Publisher	Interdisciplinary Graduate School of Engineering Sciences, Kyushu University
Publisher	九州大学大学院総合理工学府
Date	2021-02
Source Title	Engineering sciences reports, Kyushu University
Vol	42
Issue	2
First Page	18
Last Page	21
Publication Type	Version of Record
Access Rights	open access
JaLC DOI	https://doi.org/10.15017/4479148
Abstract	A variety of chiral silacyclopentanes having asymmetric silicon were synthesized based on the stereospecific substitution at C4 carbon of silacyclopentenols. Mitsunobu reaction and Tsuji-Trost reactio...n of silacyclopentenols provided substitution products with inversion and retention of C4 stereochemistry, respectively. The thus obtained substitution products can be converted into novel silacyclopentane amine, and carboxylic acids in stereospecific manner.show more

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Record ID	4479148
Subject Terms	chiral silicon molecule
	silacyclopentanes
	Mitsunobu reaction
	Tsuji-Trost reaction
ISSN	1346-7883
NCID	AA1147319X
Funding Information	Funder Name 日本学術振興会 Japan Society for the Promotion of Science Award Number 20H05677 Award Title キラル分子を光学活性体として得る革新的手法DYASINの開発 Development of DYASIN: Novel Approach to Enantioenriched Chiral Molecules
	Funder Name 日本学術振興会 Japan Society for the Promotion of Science Award Number 20H02743 Award Title キラルケイ素分子の精密合成法開発と新規生物活性分子創製への展開
	Funder Name 文部科学省先端研究基盤共用促進事業 Award Number JPMXS0422300120
Created Date	2021.06.15
Modified Date	2021.06.15