| Creator |
|
|
|
|
|
|
|
|
|
|
|
| Language |
|
| Publisher |
|
| Date |
|
| Source Title |
|
| Vol |
|
| Issue |
|
| First Page |
|
| Publication Type |
|
| Access Rights |
|
| Rights |
|
| Related DOI |
|
| Related DOI |
|
| Related URI |
|
| Related HDL |
|
| Abstract |
5-Hydroxymethylfurfural (HMF) was synthesized from monosaccharides by a biphasic reaction system using a microreactor. The biphasic reaction system realized an immediate extraction and stabilization o...f product HMF, which further degrades under the reaction conditions. Segmented flow was utilized for an efficient reaction−extraction tool. The effect of extraction ability was evaluated based on the extraction phase/ reaction phase partition coefficient of HMF. A Lewis acid catalyst was introduced to overcome the obstacle of the reaction, which was clarified as the isomerization of glucose to fructose, and improved the HMF yield to 85 mol % under the condition of T = 180 °C and τ = 47 min. The recovery of the product HMF was also examined using a constructed microextraction system, and HMF was selectively recovered from the extraction phase.show more
|
Export Mendeley
3053978