<departmental bulletin paper>
Synthesis and Stereochemical Behavior of Ketoester Derivatives having trans -Cyclononene Skeleton
Creator | |
---|---|
Language | |
Publisher | |
Date | |
Source Title | |
Vol | |
Issue | |
First Page | |
Last Page | |
Publication Type | |
Access Rights | |
JaLC DOI | |
Related DOI | |
Related URI | |
Relation | |
Abstract | It has been found that the enolate formation followed by the alkylation of cyclic ketoester 2 provides (pR*, S*)-1 predominantly as a kinetic product. Planar chirality of 1 is labile at ambient temper...ature, hence (pR*, S*)-1 easily isomerizes to thermodynamically more favorable (pS*, S*)-1.show more |
Hide fulltext details.
File | FileType | Size | Views | Description |
---|---|---|---|---|
full-32-3-4 | 1.84 MB | 385 |
Details
Record ID | |
---|---|
Peer-Reviewed | |
Subject Terms | |
ISSN | |
NCID | |
Created Date | 2010.11.16 |
Modified Date | 2020.11.27 |