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A highly dispersive supported nickel catalyst was in situ prepared by decomposing nickel tetracarbonyl onto ZSM- 5 zeolite, respectively. Unexpectedly, amorphous nickel was formed onto ZSM-5. Strong i...nteraction between supported nickel and the support is proved. Catalytic hydrogenations of arenes, i.e. durene, anthracene, phenanthrene and the heavy mixture as by-products derived from methanol-to-gasoline conversion, over the catalysts were examined. Ni/ZSM-5 shows a dramatic activity for deep hydrogenation of arenes and complete saturation of arenes can be achieved over the catalyst.続きを見る
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Mendeley出力
abstract_16