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Catalyst Design of Novel Nickellacyclic Complexes for Ethylene Polymerization

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Abstract Azanickelacyclopentene complexes were synthesized and their molecular structures are determined by X-ray crystallographic analysis. These complexes showed good reactivity toward polymerization of ethy...lene in the presence pf pMAO as the cocatalyst to give polyethylene. The effect of increased ragidity of a nickellacycle sleleton and fixation of iminoacyl moiety in a coordination plane for catalytic is discussed.show more

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Created Date 2010.08.12
Modified Date 2020.11.17

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