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Abstract |
Azanickelacyclopentene complexes were synthesized and their molecular structures are determined by X-ray crystallographic analysis. These complexes showed good reactivity toward polymerization of ethy...lene in the presence pf pMAO as the cocatalyst to give polyethylene. The effect of increased ragidity of a nickellacycle sleleton and fixation of iminoacyl moiety in a coordination plane for catalytic is discussed.show more
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