Metacyclophane and Related Compounds. 22. Bromination of 8,16-Dimethyl-5-nitro[2.2]metacyclophane with Bromine and N-Bromosuccinimide - Collections

＜departmental bulletin paper＞
Metacyclophane and Related Compounds. 22. Bromination of 8,16-Dimethyl-5-nitro[2.2]metacyclophane with Bromine and N-Bromosuccinimide

Creator	Author PID L000977 Creator Name Tashiro, Masashi 田代, 昌士タシロ, マサシ Affiliation Affiliation Name Department of Molecular Science and Technology, Interdisciplinary Graduate School of Engineering Sciences, Kyushu University
	Creator Name Takezaki, Yoshinori 竹崎, 義則タケザキ, ヨシノリ Affiliation Affiliation Name Department of Molecular Science and Technology, Interdisciplinary Graduate School of Engineering Sciences, Kyushu University
	Author PID L001170 Creator Name Takeshita, Michinori 竹下, 道範タケシタ, ミチノリ Affiliation Affiliation Name Department of Molecular Science and Technology, Interdisciplinary Graduate School of Engineering Sciences, Kyushu University
	Author PID L000929 Creator Name Tsuge, Akihiko 柘植顕彦ツゲ, アキヒコ Affiliation Affiliation Name Department of Molecular Science and Technology, Interdisciplinary Graduate School of Engineering Sciences, Kyushu University
	Creator Name Yamato, Takehiko 大和, 武彦ヤマト, タケヒコ Affiliation Affiliation Name Department of Industrial Chemistry, Faculty of Science and Engineering, Saga University
Language	English
Publisher	九州大学大学院総合理工学研究科
Publisher	Interdisciplinary Graduate School of Engineering Sciences, Kyushu University
Date	1988-09-30
Source Title	Engineering sciences reports, Kyushu University
Vol	10
Issue	2
First Page	175
Last Page	179
Publication Type	Version of Record
Access Rights	open access
JaLC DOI	https://doi.org/10.15017/17721
Related DOI	九州大学大学院総合理工学研究科報告 \|\| 10(2) \|\| p175-179
	Engineering sciences reports, Kyushu University \|\| 10(2) \|\| p175-179
	http://www.tj.kyushu-u.ac.jp/
	http://www.tj.kyushu-u.ac.jp/info/online/
Related URI	九州大学大学院総合理工学研究科報告 \|\| 10(2) \|\| p175-179
	Engineering sciences reports, Kyushu University \|\| 10(2) \|\| p175-179
	http://www.tj.kyushu-u.ac.jp/
	http://www.tj.kyushu-u.ac.jp/info/online/
Relation	九州大学大学院総合理工学研究科報告 \|\| 10(2) \|\| p175-179
	Engineering sciences reports, Kyushu University \|\| 10(2) \|\| p175-179
	http://www.tj.kyushu-u.ac.jp/
	http://www.tj.kyushu-u.ac.jp/info/online/
Abstract	When 8,16-dimethyl-5-nitro [2.2] metacyclophane (7) was treated with bromine under day light in the absence or in the presence of Fe powder, a mixture of 16-bromomethyl-8-methyl-5-nitro [2.2] MCP (8a)... and 8,16-bis (bromoethyl)-5-nitro [2.2]MCP (8a) or a mixture of 5-bromo-8,16-dimethyl-13-nitro [2.2] MCP (10) and 5-bromo-8-bromomethyl-16-methyl-13-nitro [2.2] MCP (11) were obtained, respectively. However, under shielding from light, the former reaction gave no product and the latter reaction afforded 10 in 91% yield. Bromiantion of 7 with 1.2 equivalents of NBS afforded 8a, and brominatinon with 2.5 equivalents of NBS afforded 8b.show more

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Record ID	17721
Peer-Reviewed	Refereed
ISSN	0388-1717
NCID	AN00055101
Created Date	2010.06.12
Modified Date	2020.12.15

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＜departmental bulletin paper＞ Metacyclophane and Related Compounds. 22. Bromination of 8,16-Dimethyl-5-nitro[2.2]metacyclophane with Bromine and N-Bromosuccinimide

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＜departmental bulletin paper＞
Metacyclophane and Related Compounds. 22. Bromination of 8,16-Dimethyl-5-nitro[2.2]metacyclophane with Bromine and N-Bromosuccinimide