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＜departmental bulletin paper＞
Synthetic Photochemistry. XXXI. The Cycloaddition Reaction of Myrcene with 2,4-Dioxopentanoate : A Facile Synthesis of a Versatile Intermediate for Cycloneryl Derivatives
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| Abstract | Abstract Methyl 2,4-dioxopentanoate and myrcene smoothly afforded the photoadducts by irradiation with a high-pressure mercury lamp. The (2+2)π adducts were selectively resulted from the conjugated do...uble bond moiety. Reductive cyclization of the adduct afforded cycloneryl derivatives, whose further chemical conversion were carried out.show more |
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| Created Date | 2010.06.12 |
| Modified Date | 2020.11.27 |