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Synthetic Photochemistry. XXXI. The Cycloaddition Reaction of Myrcene with 2,4-Dioxopentanoate : A Facile Synthesis of a Versatile Intermediate for Cycloneryl Derivatives
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概要 | Abstract Methyl 2,4-dioxopentanoate and myrcene smoothly afforded the photoadducts by irradiation with a high-pressure mercury lamp. The (2+2)π adducts were selectively resulted from the conjugated do...uble bond moiety. Reductive cyclization of the adduct afforded cycloneryl derivatives, whose further chemical conversion were carried out.続きを見る |
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登録日 | 2010.06.12 |
更新日 | 2020.11.27 |