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A Metal-Supported-SOFC (MS-SOFC) has been modified by infiltrating a non-noble metal ceria-zirconia supported cobalt (Co/CZ) internal reforming catalyst to improve its reforming activity and inhibit t...he carbon deposition or coking under ethanol steam reforming conditions. Non-noble metal catalysts can still be deactivated during long-term cell operation in a severe coking-inducing environment. Therefore, an in-situ regeneration procedure was performed by pulsing air into the anode surface to burn the deposited carbon on the anode and catalyst layer during the cell operation. Upon the cell regeneration steps, the cell voltage was recovered to its initial condition at ~0.8 V, while the maximum current density of the cell (at 0.35 V) showed up to 117% recovery under H₂ and ethanol. These data show that the air pulsing regeneration steps in the MS-SOFC can improve the lifetime by removing the coking deposit within the anode and further enhancing its electrochemical and catalytic activity.続きを見る
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