<会議発表論文>
Diffusionless Electrochemistry of Cytochrome c Covalently Immobilized on 11 Carboxyundecanethiol Monolayer Electrode

作成者
本文言語
出版者
発行日
収録物名
開始ページ
終了ページ
会議情報
出版タイプ
アクセス権
権利関係
関連DOI
関連URI
関連HDL
概要 Cytochrome c molecules were covalently immobilized on a self-assembled monolayer (SAM) electrode from 11-carboxyalkanethiol. The electrode with the protein/SAM/gold interfacial structure gave well-def...ined, stable redox waves which were attributed for the direct electron transfer (ET) reaction of the proteins. The formal potential was 234±4 mV (vs SHE, n=8) and the electroactive surface coverage of the protein was estimated to be 9.3±2.3 pmol cm^<-2> (n=8) which was consistent to submonolayer coverage. Detailed analysis for the ET reaction gave a rate constant of 2.5±1.0 s^<-1> (n=8).続きを見る

本文ファイル

pdf 7324374 pdf 51.3 KB 7  

詳細

レコードID
助成情報
登録日 2024.11.26
更新日 2024.12.12