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Impregnation Effect of Iron (Fe) and Cobalt (Co) on ZSM-5 Zeolite Catalyst from Rice Husk Ash and Coal Fly Ash for Methanol Synthesis

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概要 The methanol production process is a major issue due to the importance of methanol applications in transportation and other chemical industries. Selective catalysis of methane to methanol conversion u...sing specific catalysts is one of numerous efficient methanol production processes now being developed by researchers worldwide. In the current study, we investigated the effectiveness of ZSM-5 zeolite-supported iron oxide and cobalt oxide as catalytic agents. The ZSM-5 zeolite employed (synthesized ZSM-5) was developed through a non-template approach by using ash from rice husk (RHA) and fly ash from coal (CFA). Wet impregnation method was used to impregnate the synthesized ZSM-5 with iron (Fe) and cobalt (Co), and a commercial ZSM-5 was likewise impregnated with Fe and Co for comparison. XRD, BET, and SEM-EDX ware used to examine the zeolite structure of the synthesized ZSM-5, and results discovered that the zeolite had been successfully created from rice husk ash and coal fly ash. The synthesized ZSM-5 samples were tested in a batch reactor for an hour at 423 K and 4 bars of initial methane pressure to accomplish methane to methanol conversion in an effort to quantify the catalytic activity. The results revealed that Fe impregnation of synthesized ZSM-5 zeolite had a greater effect on increasing methanol yield than Co impregnation. The catalytic performance test was impacted by Fe and Co impregnation in ZSM-5. This shows that the methanol yield of the synthesized ZSM-5 can be increased by Fe impregnation to 13.12% from 10.04% without it.続きを見る

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登録日 2023.10.12
更新日 2024.02.21

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