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| 概要 |
The Mitsunobu reaction of tropolone with 2-(perfluoroalkyl) ethanols, low-reactive nucleophiles, afforded 2-(polyfluoroalkoxy) tropones in good yields. The high-pressure (300MPa) Diels-Alder reaction ...of several 2-(polyfluoroalkoxy) tropones with C_<60> gave the [4+2] cycloadducts. Modification of the fullerene with polyfluoroalkoxylated homobarrelenone framework resulted in the great enhancement of solubility in common organic solvents.続きを見る
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