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We report conduction measurements on the clean, free surface of transparent insulating BaTiO_3 single crystals in high vacuum. We find that the insulating BaTiO3 crystals exhibit surface conductance t...hat is dependent on the spontaneous polarization, whereas no conduction perpendicular to the surface is observed. The surface conduction shows semimetallic temperature dependence and persists down to at least 100 K. The observations suggest a two-dimensional electron on a clean, free ferroelectric surface that may be regarded as a ferroelectric metal. The results have important implications for understandings of the fundamental properties of ferroelectrics, the size effect, and ferroelectric devices.続きを見る
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Mendeley出力
PhysRevLett.86.332
link_26371