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In order to investigate the electrochemical properties, several p-tropoquinones were synthesized. In their cyclic voltammgrams, two redox couples appeared and their potentials were affected by substit...uents. In some cases, a chemical reaction was accompanied during reduction-oxidation processes. Preparative electrolysis was performed to determine the structure of the product. It was concluded that the reversibility of the reduction-oxidation processes in p-tropoquinones was similar to those of p-benzoquinones and 1,4-naphthoquinones from the substituent effect to the oxidation-reduction potentials of p-tropoquinones.続きを見る
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