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＜departmental bulletin paper＞
A Formal Total Synthesis of Colchicine via the Scott's Intermediate. Palladium (0)-Mediated meta-Ethynylation of a Tropolone Derivative
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| Abstract | Colchicine was formally synthesized from 4-hydroxytropolone in a few-step sequence. The key step of the synthesis is palladium (0)-catalyzed ethynylation of 4-(trifluoromesyloxy)-2-methoxytropone. The... present method has a potential in synthesizing various structurally modified colchicine derivatives.show more |
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| Created Date | 2009.04.22 |
| Modified Date | 2020.11.17 |