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＜departmental bulletin paper＞
Synthetic Photochemistry. LIX. Intramolecular Photocycloaddition of 2-(3-Butenyl)-2, 6-dimethyl-4H-1, 3-dioxin-4-one
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| Abstract | 2-(3-Butenyl)-2, 6-dimethyl-4H-1, 3-dioxin-4-one, an adduct of diketene to 1-hexen-5-one, formed a single photocycloadduct with opposite regioselectivity against the ordinary manner. This could be exp...lained in terms of a non-bonding interaction between two endo-hydrogens of the cage-shaped photocyclisates.show more |
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| Created Date | 2009.04.22 |
| Modified Date | 2023.11.24 |